Investigation of chemical quality and oil and metal contaminations in surface runoff of Shazand distribution and refinery complex, Arak

AuthorsAbdorreza Vaezihir- Mohammad Ranjdoust- Ali Kadkhodaei- Alireza Gholmohammadi
JournalHuman and Environment
Paper TypeFull Paper
Published At۲۰۲۲-۱۲-۰۶
Journal GradeScientific - research
Journal TypeTypographic
Journal CountryIran, Islamic Republic Of

Abstract

Pollution ‏‏of ‏‏surface ‏‏water ‏‏by ‏‏hydrocarbon ‏‏compounds ‏‏released ‏‏from ‏‏the refineries, ‏‏storage ‏‏tanks ‏‏and ‏‏convay ‏‏pipline ‏‏is ‏‏very ‏‏possible ‏‏and ‏‏need ‏‏to ‏‏be ‏‏addressed ‏‏with ‏‏high sensitivity.‏‏‏‏ Purpose‏‏ of ‏‏this ‏‏study ‏‏is ‏‏investigation‏‏ of ‏‏contamination ‏‏and ‏‏hydrochemical ‏‏properties ‏‏of ‏‏runoff waters ‏‏at ‏‏Shazand ‏‏refinery. ‏‏Water ‏‏samples ‏‏collected ‏‏and ‏‏analysed ‏‏for ‏‏major ‏‏ions ‏‏and ‏‏oil ‏‏and ‏‏metal contaminants. Twoelve ‏‏samples ‏‏were ‏‏collected ‏‏from ‏‏surface ‏‏waters ‏‏of ‏‏the ‏‏refinery ‏‏and ‏‏were analyzed‏‏ for‏‏ oil ‏‏materials, ‏‏some ‏‏heavy ‏‏metals, ‏‏nutrients‏‏ and‏‏ major‏‏ ions.‏‏ Some‏‏ other‏‏ parameters‏‏ like ‏‏EC and ‏‏pH‏‏ were‏‏ meseared‏‏ in ‏‏situe. According ‏‏to ‏‏the ‏‏results, ‏‏the ‏‏runoff ‏‏in ‏‏some ‏‏parts ‏‏of ‏‏the ‏‏refinery ‏‏shows ‏‏contamination ‏‏by benzene.‏‏ Ethylbenzene‏‏ concentration,‏‏ however, ‏‏is‏‏ less‏‏ than‏‏ maximum ‏‏permissible ‏‏level‏‏ and‏‏ no‏‏ evidence of ‏‏MTBE‏‏ and‏‏ toluene ‏‏was‏‏ detected. Pollution ‏‏by ‏‏benzene ‏‏can ‏‏be ‏‏due ‏‏to ‏‏pollutants ‏‏released ‏‏from ‏‏the ‏‏refining process‏‏ and‏‏ spilling‏‏ of‏‏ oil.‏‏ A‏‏part‏‏ of ‏‏BTEX ‏‏pollutants ‏‏in ‏‏surface‏‏ water‏‏ can ‏‏be‏‏ came‏‏ from ‏‏atmospheric washout‏‏ during ‏‏precipitation.‏‏ No ‏‏evidents‏‏ of ‏‏MTBE‏‏ detected ‏‏in ‏‏the ‏‏samples. ‏‏‏It‏‏ should‏‏ be ‏‏mentioned‏‏ that BTEX ‏‏and ‏‏MTBE ‏‏are ‏‏volatile ‏‏components ‏‏and ‏‏cannot ‏‏be ‏‏survived ‏‏in ‏‏surface ‏‏water ‏‏for ‏‏a ‏‏long ‏‏time. Chemical‏‏ parameters‏‏ such‏‏as ‏‏EC‏‏ and ‏‏ions‏‏ concentaration ‏‏in ‏‏the‏‏ surface ‏‏water ‏‏in ‏‏the‏‏ central‏‏ area ‏‏of ‏‏the refinery ‏‏shows ‏‏an ‏‏anomaly ‏‏which ‏‏would ‏‏be ‏‏related‏‏ to‏‏ the ‏‏industrial ‏‏activites.‏‏ The‏‏ runoff‏‏ of‏‏ this ‏‏part‏‏ of‏‏ the‏‏ refinery ‏‏is ‏‏less‏‏ suitable ‏‏for ‏‏industrial‏‏ and‏‏ agricultural‏‏ usges.‏‏